1-(Pyridin-2-yl)-2-[2-(trifluoromethyl)benzyl]-3-[2-(trifluoromethyl)phenyl]propan-1-one
نویسندگان
چکیده
The title compound, C(23)H(17)F(6)NO, crystallizes with two mol-ecules in the asymmetric unit. The mol-ecules assume an approximate propellar shape, with the three aromatic rings being bent with respect to the plane formed by the C atoms that are connected to the methine C atom [dihedral angles: pyridyl 67.49 (3)°, phenyl 56.82 (4)° and phenyl 77.21 (6)° in one mol-ecule, and corresponding angles of 71.60 (6), 53.68 (4) and 77.53 (6)° in the second mol-ecule].
منابع مشابه
1-(4,5,6,7-Tetrahydrothieno[3,2-c]pyridin-5-yl)-2-{4-[3-(trifluoromethyl)phenyl]piperazin-1-yl}ethanone
In the title mol-ecule, C(20)H(22)F(3)N(3)OS, the piperazine ring has a chair conformation, and the N-C(=O)-C-N torsion angle is -59.42 (14)°. In the crystal, weak C-H⋯O and C-H⋯π inter-actions link the mol-ecules into layers parallel to (101).
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In the title compound, [Pd(CH(3))(C(26)H(14)F(18)NOP)(C(2)H(3)N)][SbF(6)]·0.5CH(2)Cl(2), the Pd(2+) cation has a distorted square-planar environment, being coordinated by the acetonitrile [Pd-N = 2.078 (8) Å] and methyl [Pd-C = 2.052 (9) Å] groups and the bidentate ligand 2-(1-{bis-[2,4,6-tris-(trifluoro-meth-yl)phen-yl]phosphan-yloxy}-1-methyl-eth-yl)pyridine (L). In L, one -CF(3) group is rot...
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In the title compound, C(19)H(14)F(3)N(3), the dihedral angles between the mean planes of the indole ring and the 4-CF(3)-phenyl and imidazole rings are 54.95 (4) and 61.36 (7)°, respectively.
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